Highly enantioselective hydroaminoalkylation of secondary amines catalyzed by group 5 metal amides with chiral biarylamidate ligands.
نویسندگان
چکیده
A highly enantioselective group 5 metal amide catalyst system is reported for the hydroaminoalkylation of secondary amines to give chiral amines in good yields with excellent ee values (up to 93%) by loading of 5% precatalyst.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 46 34 شماره
صفحات -
تاریخ انتشار 2010